Light-Induced Single-Electron Transfer Processes involving Sulfur Anions as Catalysts,Journal of the American Chemical Society

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Light-Induced Single-Electron Transfer Processes involving Sulfur Anions as Catalysts
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2021-09-20 , DOI: 10.1021/jacs.1c07785
Shun Wang ₁ , Hua Wang ₁ , Burkhard König ₁

Affiliation

Photoredox catalysis has evolved as an attractive approach to enable a wide variety of chemical reactions with high selectivity under mild conditions. The development of novel photocatalytic systems is key to obtaining new reactivity and improving their catalytic performances. In this context, cost-effective organic anion-based photocatalysts have recently attracted increasing interest. In particular, sulfur-based anionic catalysts are of interest due to their unique redox properties. This Perspective highlights and discusses recent advances in light-induced single-electron-transfer processes directly involving sulfur anions as catalysts. The content of this Perspective is organized along the different photoinduced electron-transfer pathways between catalysts and substrates.

中文翻译：

涉及硫阴离子作为催化剂的光诱导单电子转移过程

光氧化还原催化已发展成为一种有吸引力的方法，可以在温和条件下以高选择性进行各种化学反应。开发新型光催化体系是获得新反应性和提高其催化性能的关键。在这种情况下，具有成本效益的有机阴离子基光催化剂最近引起了越来越多的兴趣。特别是，硫基阴离子催化剂因其独特的氧化还原性能而受到关注。该观点突出并讨论了直接涉及硫阴离子作为催化剂的光诱导单电子转移过程的最新进展。本透视图的内容按照催化剂和基材之间不同的光致电子转移途径进行组织。

更新日期：2021-09-29

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