Front Cover Picture: Indene Derived Phosphorus-Thioether Ligands for the Ir-Catalyzed Asymmetric Hydrogenation of Olefins with Diverse Substitution Patterns and Different Functional Groups (Adv. Synth. Catal. 19/2021),Advanced Synthesis & Catalysis

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Front Cover Picture: Indene Derived Phosphorus-Thioether Ligands for the Ir-Catalyzed Asymmetric Hydrogenation of Olefins with Diverse Substitution Patterns and Different Functional Groups (Adv. Synth. Catal. 19/2021)
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-09-17 , DOI: 10.1002/adsc.202101075
J. Margalef ₁ , M. Biosca ₁ , P. Cruz‐Sánchez ₁ , X. Caldentey ₂ , C. Rodríguez‐Escrich ₂ , O. Pàmies ₁ , M. A. Pericàs _{2,

3} , M. Diéguez ₁

Affiliation

The front cover picture, designed by Jèssica Margalef, illustrates the usefulness of a modular and easy-to-assemble catalyst design for asymmetric hydrogenation. By choosing the appropriate sulfur and phosphorus substituents on new Ir-P,S-catalysts, it is possible to hydrogenate substrates of very different nature (50 olefins in total). Improving on most catalysts reported so far, di- and E/Z-trisubstituted olefins with a variety of functional groups and coordination ability can be reduced with excellent enantioselectivities. Details can be found in the Research Article by Diéguez and co-authors (J. Margalef, M. Biosca, P. de la Cruz-Sánchez, X. Caldentey, C. Rodríguez-Escrich, O. Pàmies, M. A. Pericàs, M. Diéguez, Adv. Synth. Catal. 2021, 363, 4561–4574; DOI: 10.1002/adsc.202100069)

中文翻译：

封面图片：用于 Ir 催化的具有不同取代模式和不同官能团的烯烃的不对称氢化的茚衍生的磷-硫醚配体 (Adv. Synth. Catal. 19/2021)

所述前盖的画面，由JESSICA马加利夫设计，示出了模块化的和易于组装的催化剂的设计不对称氢化的有用性。通过在新的 Ir-P,S-催化剂上选择合适的硫和磷取代基，可以氢化性质非常不同的底物（总共 50 种烯烃）。对迄今为止报道的大多数催化剂进行改进，具有多种官能团和配位能力的二-和E / Z-三取代烯烃可以以优异的对映选择性减少。详细信息可在 Diéguez 及其合著者（J. Margalef、M. Biosca、P. de la Cruz-Sánchez、X. Caldentey、C. Rodríguez-Escrich、O. Pàmies、MA Pericàs、M. Diéguez, Adv. Synth. Catal. 2021，363，4561-4574; DOI: 10.1002/adsc.202100069)

更新日期：2021-10-06

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