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Ethanol sensor using gadolinia-doped ceria solid electrolyte and double perovskite structure sensing material
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2021-09-17 , DOI: 10.1016/j.snb.2021.130771
Tong Liu 1 , Tong Wang 2 , Hangfei Li 1 , Jie Su 1 , Xidong Hao 2 , Fengmin Liu 2 , Fangmeng Liu 2 , Xishuang Liang 2
Affiliation  

Mixed potential gadolinia-doped ceria (GDC)-based gas sensors using a double perovskite composite oxide (Sr2NiMoO6) were fabricated to detect ethanol. The influence of the sensing materials sintered at different temperatures on the sensor properties was investigated. The results showed that Sr2NiMoO6 annealed at 1000 °C was the most suitable sensing material for detecting ethanol due to its suitable micromorphology and high electrochemical catalytic activity. The sensor attached with Sr2NiMoO6-1000 °C displayed the highest sensitivity to 1–200 ppm ethanol at 550 °C, the response value ΔV was piecewise linearly with the logarithm of ethanol concentration, and the slopes were −8 and −51.3 mV/decade in the ranges of 1–10 ppm and 10–200 ppm ethanol, respectively. Moreover, the stability and sensing mechanism of the sensor were also investigated.



中文翻译:

使用钆掺杂氧化铈固体电解质和双钙钛矿结构传感材料的乙醇传感器

使用双钙钛矿复合氧化物(Sr 2 NiMoO 6)制造基于混合电位钆掺杂的氧化铈(GDC)的气体传感器来检测乙醇。研究了在不同温度下烧结的传感材料对传感器性能的影响。结果表明,1000℃退火的Sr 2 NiMoO 6具有合适的微观形貌和较高的电化学催化活性,是最适合检测乙醇的传感材料。附有 Sr 2 NiMoO 6的传感器-1000 °C 在 550 °C 时对 1–200 ppm 乙醇的灵敏度最高,响应值 ΔV 与乙醇浓度的对数呈分段线性关系,斜率在 1 范围内分别为 -8 和 -51.3 mV/decade分别为 –10 ppm 和 10–200 ppm 乙醇。此外,还研究了传感器的稳定性和传感机制。

更新日期:2021-09-24
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