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Synthesis and characterization of ZnGa2O4 composites and its photocatalytic properties for energy applications
Environmental Research ( IF 7.7 ) Pub Date : 2021-09-16 , DOI: 10.1016/j.envres.2021.112073
D Nathiya 1 , N M I Alhaji 1 , A R Mohamed Jahangir 2 , M Ismail Fathima 3 , Mansour K Gatasheh 4 , Ashraf Atef Hatamleh 5 , Sadaf Zehra 6 , A Ayeshamariam 7
Affiliation  

ZnGa2O4 nanocomposites have been widely used for photocatalytic degradation of industrial dyes. In this work, ZnGa2O4 was synthesized from zinc sulphate heptahydrate ZnSO4.10H2O and Gallium (III) oxide (Ga2O3) by hydrothermal method. As prepared, ZnGa2O4 nanocomposites was used as a photocatalyst degradation of three organic dyes rhodamine-B, methylene blue, and methyl orange, under ultraviolet (UV) light irradiation. The ZnGa2O4 nanocomposites structure, morphology, size and optical properties were studied by X-ray diffraction (XRD), Fourier transform Raman spectroscopy (FT-Raman), scanning electron microscopy (SEM), Transmission electron microscopes (TEM) and photoluminescence spectra (PL). Moreover, the results explained the rate-controlling mechanisms of the dye degradation process followed by second-order kinetics. After 100 min of adsorption kinetic models, the decomposition of rhodamine-B (7.2 Ct mg/L, 5.2 Ct mg/L, and 4.1 Ct mg/L), methylene blue (42.8 qt mg/g, 44.8 qt mg/g, and 45.9 qt mg/g), and methyl orange (42.8 qe mg/g, 44.8 qe mg/g, and 45.9 qe mg/g) respectively. This investigation study offers a promising method to design more efficient ZnGa2O4 nanocomposites based photocatalytic degradation of industrial organic dyes.



中文翻译:

ZnGa2O4 复合材料的合成与表征及其在能源应用中的光催化性能

ZnGa 2 O 4纳米复合材料已广泛用于工业染料的光催化降解。本工作以七水硫酸锌 ZnSO 4 为原料合成了ZnGa 2 O 4 水热法制备10H 2 O 和氧化镓 (III) (Ga 2 O 3 )。正如所制备的那样,ZnGa 2 O 4纳米复合材料被用作三种有机染料罗丹明-B、亚甲基蓝和甲基橙在紫外(UV)光照射下的光催化剂降解。ZnGa 2 O 4通过X射线衍射(XRD)、傅里叶变换拉曼光谱(FT-Raman)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和光致发光光谱(PL)研究了纳米复合材料的结构、形貌、尺寸和光学性质。此外,结果解释了染料降解过程的速率控制机制以及二级动力学。在吸附动力学模型 100 分钟后,罗丹明-B(7.2 Ct mg/L、5.2 Ct mg/L 和 4.1 Ct mg/L)、亚甲蓝(42.8 qt mg/g、44.8 qt mg/g)的分解,和 45.9 qt mg/g)和甲基橙(42.8 qe mg/g、44.8 qe mg/g 和 45.9 qe mg/g)。这项调查研究提供了一种有前途的方法来设计更高效的 ZnGa 2 O 4基于纳米复合材料的工业有机染料光催化降解。

更新日期:2021-09-21
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