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Synthesis of silanized chitosan anchored onto porous composite and its performance in fixed-bed adsorption of Cr(VI)
Journal of Environmental Chemical Engineering ( IF 7.7 ) Pub Date : 2021-09-16 , DOI: 10.1016/j.jece.2021.106353
Cesar Mario Laureano-Anzaldo 1 , Martín Esteban González-López 1 , Aida Alejandra Pérez-Fonseca 1 , Luis Emilio Cruz-Barba 1 , Jorge Ramón Robledo-Ortíz 2
Affiliation  

Chitosan was supported on a porous composite using 3-aminopropyltriethoxysilane (APTES) as silanizing agent through a simple and green method to enhance Cr(VI) uptake performance under batch and continuous-flow systems. Chemical modification was corroborated through ATR-FTIR and SEM/EDX analyses, showing a silane loading of 6.2% onto the surface of the chitosan composite. The silanized composite adsorption capacity was 18 mg/g (155 mg/gchitosan) in batch experiments. The porous nature of the adsorbent had a positive kinetic effect, achieving equilibrium after 30 min. Fixed-bed column adsorption showed an adsorption capacity of 12 mg/g (102 mg/ gchitosan). Through an alternative desorbing configuration in column regeneration, the eluted volume was minimized to less than 20% of the treated volume, enhancing the behavior of the adsorbent in multiple adsorption-desorption cycles.



中文翻译:

多孔复合材料锚定硅烷化壳聚糖的合成及其固定床吸附六价铬的性能

壳聚糖负载在多孔复合材料上,使用 3-氨基丙基三乙氧基硅烷 (APTES) 作为硅烷化剂,通过一种简单且绿色的方法来提高间歇和连续流动系统下 Cr(VI) 的吸收性能。通过 ATR-FTIR 和 SEM/EDX 分析证实了化学改性,表明壳聚糖复合材料表面的硅烷负载量为 6.2%。在批量实验中,硅烷化复合物的吸附容量为 18 mg/g(155 mg/g壳聚糖)。吸附剂的多孔性质具有积极的动力学效应,在 30 分钟后达到平衡。固定床柱吸附显示吸附容量为 12 mg/g(102 mg/g壳聚糖)。通过柱再生中的替代解吸配置,洗脱体积最小化到处理体积的 20% 以下,增强了吸附剂在多个吸附-解吸循环中的行为。

更新日期:2021-09-23
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