This review introduces recent advances in photocatalysis in discrete supramolecular fluorescent metallacycles and metallacages. The effects of metallacycles skeletons to overcome aggregation-caused quenching effect and fluorescence-resonance energy transfer for photocatalysis are discussed. The utilization of confined space in metallacages can accelerate the rate of reaction and improve the selectivity for photocatalysis.

中文翻译：

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超分子荧光金属环和金属笼中的光催化

这篇综述介绍了离散超分子荧光金属环和金属笼中光催化的最新进展。讨论了金属环骨架克服聚集引起的猝灭效应和用于光催化的荧光共振能量转移的作用。利用金属笼中的密闭空间可以加快反应速度并提高光催化的选择性。