Transition metal-catalyzed organic reactions in undivided electrochemical cells,Chemical Science

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Transition metal-catalyzed organic reactions in undivided electrochemical cells
Chemical Science ( IF 7.6 ) Pub Date : 2021-08-24 , DOI: 10.1039/d1sc04011a
Cong Ma ₁ , Ping Fang ₁ , Dong Liu ₁ , Ke-Jin Jiao ₁ , Pei-Sen Gao ₁ , Hui Qiu ₁ , Tian-Sheng Mei ₁

Affiliation

Transition metal-catalyzed organic electrochemistry is a rapidly growing research area owing in part to the ability of metal catalysts to alter the selectivity of a given transformation. This conversion mainly focuses on transition metal-catalyzed anodic oxidation and cathodic reduction and great progress has been achieved in both areas. Typically, only one of the half-cell reactions is involved in the organic reaction while a sacrificial reaction occurs at the counter electrode, which is inherently wasteful since one electrode is not being used productively. Recently, transition metal-catalyzed paired electrolysis that makes use of both anodic oxidation and cathodic reduction has attracted much attention. This perspective highlights the recent progress of each type of electrochemical reaction and relatively focuses on the transition metal-catalyzed paired electrolysis, showcasing that electrochemical reactions involving transition metal catalysis have advantages over conventional reactions in terms of controlling the reaction activity and selectivity and figuring out that transition metal-catalyzed paired electrolysis is an important direction of organic electrochemistry in the future and offers numerous opportunities for new and improved organic reaction methods.

中文翻译：

整体电化学电池中过渡金属催化的有机反应

过渡金属催化有机电化学是一个快速发展的研究领域，部分原因是金属催化剂能够改变给定转化的选择性。这一转化主要集中在过渡金属催化的阳极氧化和阴极还原方面，并在这两个领域都取得了很大的进展。通常，有机反应中仅涉及其中一个半电池反应，而对电极处发生牺牲反应，这本质上是一种浪费，因为一个电极没有得到有效使用。近年来，同时利用阳极氧化和阴极还原的过渡金属催化配对电解引起了广泛关注。该观点重点介绍了各类电化学反应的最新进展，并相对关注过渡金属催化的配对电解，展示了涉及过渡金属催化的电化学反应在控制反应活性和选择性方面比传统反应具有优势，并指出：过渡金属催化配对电解是未来有机电化学的一个重要方向，为新的和改进的有机反应方法提供了众多机会。

更新日期：2021-09-16

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