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Surfactant induced self-assembly to prepare a vanadium nitride/N,S co-doped carbon high-capacitance anode material
Chemical Communications ( IF 4.3 ) Pub Date : 2021-09-06 , DOI: 10.1039/d1cc04143f Tianqi He 1 , Qiuping Zhao 2 , Qianghong Wu 1 , Junlei Zhang 1 , Fen Ran 1
Chemical Communications ( IF 4.3 ) Pub Date : 2021-09-06 , DOI: 10.1039/d1cc04143f Tianqi He 1 , Qiuping Zhao 2 , Qianghong Wu 1 , Junlei Zhang 1 , Fen Ran 1
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The mechanism of the reaction of melamine (C3H6N6) with ammonium metavanadate and the critical role of the surfactant in this reaction were investigated. The results indicate that the complex is obtained via the reaction of C3H6N6 with VO3- after the elimination of –NH2, and the surfactant can modulate the microstructure. In addition, a vanadium nitride/N,S co-doped carbon material fabricated from the above complex exhibits a specific capacitance of 422.0 F g−1 at 0.5 A g−1. This method provides a new route for the synthesis of vanadium nitride/carbon materials.
中文翻译：
表面活性剂诱导自组装制备氮化钒/N,S共掺杂碳高电容负极材料
研究了三聚氰胺（C 3 H 6 N 6）与偏钒酸铵的反应机理以及表面活性剂在该反应中的关键作用。结果表明，该配合物获得经由C的反应3 ħ 6 Ñ 6与VO 3 -消除-NH后2，和表面活性剂可以调节微结构。此外，氮化物/ N钒，S共掺杂的碳材料从422.0 F G上述复合表现出比电容制造-1在0.5 A克-1. 该方法为氮化钒/碳材料的合成提供了一条新途径。
更新日期：2021-09-16
中文翻译：
表面活性剂诱导自组装制备氮化钒/N,S共掺杂碳高电容负极材料
研究了三聚氰胺（C 3 H 6 N 6）与偏钒酸铵的反应机理以及表面活性剂在该反应中的关键作用。结果表明，该配合物获得经由C的反应3 ħ 6 Ñ 6与VO 3 -消除-NH后2，和表面活性剂可以调节微结构。此外，氮化物/ N钒，S共掺杂的碳材料从422.0 F G上述复合表现出比电容制造-1在0.5 A克-1. 该方法为氮化钒/碳材料的合成提供了一条新途径。
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