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Environmentally benign and durable superhydrophobic coatings based on short fluorocarbon chain siloxane modified halloysite nanotubes for oil/water separation
Colloids and Surfaces A: Physicochemical and Engineering Aspects ( IF 4.9 ) Pub Date : 2021-09-15 , DOI: 10.1016/j.colsurfa.2021.127540
Penglin Cai 1 , Kaiying Di 1 , Jiashuainan Lv 1 , Sha Li 1 , Xiaoting Chen 1
Affiliation  

Fluorinated siloxane (F-Si(OCH3)3) was synthesized from perfluoro (2-methyl-3-oxyhexyl) fluorine and N- (β-aminoethyl) -γ-aminopropyltrimethoxy silane, and then was used for hydrophobic modification of halloysite nanotubes (F-HNTs). A mixture of epoxy resin and F-HNTs was sprayed onto the surface of the stainless steel mesh. F-HNTs enhanced the surface roughness and reduced the surface energy, giving the mesh superhydrophobic/superlipophilic properties. The static water contact angle of coated mesh can reach 155.4 ± 0.3°. A series of oil and water mixtures can be separated, and the separation efficiency was higher than 97.8 ± 0.3%. After 50 cycles, the separation efficiency was still higher than 96.2 ± 0.5%. The coating mesh also had high separation efficiency for oil-water mixtures with different volume ratios and pH values. More importantly, the coated mesh still showed good stability in the harsh test conditions, such as strong acid, strong alkali, sand-paper wear and so on. Since the preparation of the coated mesh has the advantages of simplicity, scalability, and economy, it is expected to be applied on a large scale in the field of oil-water separation in the future.



中文翻译:

基于短氟碳链硅氧烷改性埃洛石纳米管的环保耐用超疏水涂层用于油水分离

氟化硅氧烷 (F-Si(OCH 3 ) 3)由全氟(2-甲基-3-氧己基)氟和N-(β-氨基乙基)-γ-氨基丙基三甲氧基硅烷合成,然后用于埃洛石纳米管(F-HNTs)的疏水改性。将环氧树脂和 F-HNT 的混合物喷涂到不锈钢网的表面。F-HNTs 增强了表面粗糙度并降低了表面能,赋予了网状超疏水/超亲油特性。涂层网的静态水接触角可达155.4±0.3°。可分离一系列油水混合物,分离效率高于97.8±0.3%。50次循环后,分离效率仍高于96.2±0.5%。涂层网对不同体积比和pH值的油水混合物也有很高的分离效率。更重要的是,涂层网在强酸、强碱、砂纸磨损等严苛测试条件下仍表现出良好的稳定性。由于涂层网的制备具有简单、可扩展性和经济性等优点,有望在未来在油水分离领域得到大规模应用。

更新日期:2021-09-23
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