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Bimodal Floquet theory of phase-modulated heteronuclear decoupling experiments in solid-state NMR spectroscopy
The Journal of Chemical Physics ( IF 3.1 ) Pub Date : 2021-09-08 , DOI: 10.1063/5.0061883
Rajat Garg 1 , Manoj Kumar Pandey 2 , Ramesh Ramachandran 1
Affiliation  

A prescription based on bimodal Floquet theory is proposed to describe the nuances of phase-modulated supercycled decoupling experiments in solids. The frequency dependent interaction frames relevant to a particular supercycle are identified to facilitate faster convergence of perturbation corrections to the derived effective Hamiltonians. In contrast to silico-based methods, the proposed analytic method offers an attractive platform for faster optimization of experiments in solids. Additionally, the relevance of supercycling at ultrafast spinning conditions is also discussed.

中文翻译:

固态核磁共振波谱中相位调制异核解耦实验的双峰 Floquet 理论

提出了一种基于双峰 Floquet 理论的处方来描述固体中相位调制超循环解耦实验的细微差别。确定与特定超级循环相关的频率相关相互作用框架,以促进扰动校正更快地收敛到导出的有效哈密顿量。与基于硅的方法相比,所提出的分析方法为更快地优化固体实验提供了一个有吸引力的平台。此外,还讨论了超快纺条件下超级循环的相关性。
更新日期:2021-09-15
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