Cu2O-Catalyzed Conversion of Benzyl Alcohols Into Aromatic Nitriles via the Complete Cleavage of the C≡N Triple Bond in the Cyanide Anion,Chemistry - An Asian Journal

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Cu2O-Catalyzed Conversion of Benzyl Alcohols Into Aromatic Nitriles via the Complete Cleavage of the C≡N Triple Bond in the Cyanide Anion
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2021-09-15 , DOI: 10.1002/asia.202100776
Wenbo Liu ₁ , Peichen Tang ₂ , Yi Zheng ₁ , Yun-Lai Ren ₁ , Xinzhe Tian ₁ , Wankai An ₁ , Xianfu Zheng ₁ , Yinggang Guo ₁ , Zhenpeng Shen ₁

Affiliation

A catalytic method was developed for the nitrogen transfer from cyanide anion to an alcohol via the complete cleavage of the C≡N triple bond using Phen/Cu₂O as the catalyst. The present condition allowed various benzyl alcohols to be smoothly converted into aromatic nitriles in moderate to high yields.