Stable CAAC-based Ruthenium Complexes for Dynamic Olefin Metathesis Under Mild Conditions,ChemCatChem

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Stable CAAC-based Ruthenium Complexes for Dynamic Olefin Metathesis Under Mild Conditions
ChemCatChem ( IF 3.8 ) Pub Date : 2021-09-14 , DOI: 10.1002/cctc.202101172
Alexander Kravchenko ₁ , Brian J.J. Timmer ₁ , A. Ken Inge ₂ , Maurice Biedermann ₁ , Olof Ramström ₃

Affiliation

Balance for dynamics: The efficiency of catalysts based on cyclic (alkyl)(amino) carbenes (CAACs) has been evaluated in benchmark olefin metathesis reactions under mild conditions. The catalysts displayed a delicate balance between activity and stability, where good performance and functional group tolerance could be identified. Well-balanced catalysts allowed for the generation of dynamic systems of olefins.

中文翻译：

用于温和条件下动态烯烃复分解的稳定的 CAAC 基钌配合物

动力学平衡：已在温和条件下的基准烯烃复分解反应中评估了基于环状（烷基）（氨基）卡宾 (CAAC) 的催化剂的效率。催化剂在活性和稳定性之间表现出微妙的平衡，可以确定良好的性能和官能团耐受性。平衡良好的催化剂允许生成烯烃的动态系统。

更新日期：2021-11-22

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