Electrochemically promoted oxidative α-cyanation of tertiary and secondary amines using cheap AIBN,Organic & Biomolecular Chemistry

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Electrochemically promoted oxidative α-cyanation of tertiary and secondary amines using cheap AIBN
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2021-09-04 , DOI: 10.1039/d1ob01416a
Qing-Wen Gui _{1,

2} , Zhi-Yuan Xiong ₁ , Fan Teng ₁ , Tian-Cheng Cai ₁ , Qiang Li _{1,

3} , Wenxia Hu ₁ , Xiaoli Wang ₁ , Jialing Yu ₁ , Xiaoying Liu ₁

Affiliation

The electrochemical α-cyanation of tertiary and secondary amines has been developed by using a cheap cyanide reagent, azobisisobutyronitrile (AIBN). The CN radical, generated through n-Bu₄NBr-meidated electrochemical oxidation, participates in a novel α-cyanation reaction under exogenous oxidant-free conditions.

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