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Electrochemically promoted oxidative α-cyanation of tertiary and secondary amines using cheap AIBN
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2021-09-04 , DOI: 10.1039/d1ob01416a
Qing-Wen Gui 1, 2 , Zhi-Yuan Xiong 1 , Fan Teng 1 , Tian-Cheng Cai 1 , Qiang Li 1, 3 , Wenxia Hu 1 , Xiaoli Wang 1 , Jialing Yu 1 , Xiaoying Liu 1
Affiliation  

The electrochemical α-cyanation of tertiary and secondary amines has been developed by using a cheap cyanide reagent, azobisisobutyronitrile (AIBN). The CN radical, generated through n-Bu4NBr-meidated electrochemical oxidation, participates in a novel α-cyanation reaction under exogenous oxidant-free conditions.

中文翻译:

使用廉价 AIBN 电化学促进叔胺和仲胺的氧化 α-氰化

通过使用廉价的氰化物试剂偶氮二异丁腈 (AIBN) 开发了叔胺和仲胺的电化学 α-氰化。通过n -Bu 4 NBr 介导的电化学氧化产生的 CN 自由基在无外源氧化剂的条件下参与了一种新的 α-氰化反应。
更新日期:2021-09-15
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