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Comparative study on thermal and electrical transport properties of hexagonal boron nitride and reduced graphene oxide/epoxy nanocomposite by transient plane source techniques and impedance spectroscopy
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2021-09-14 , DOI: 10.1007/s10854-021-06994-0
Akash M. Chandran 1 , S. Varun 1 , Prasanna Kumar S. Mural 1
Affiliation  

Within the scope of the study, the thermal conductivity (TC) and thermal diffusivity (TD) of hexagonal boron nitride (h-BN) and reduced graphene (r-GO)-based epoxy nanocomposites were investigated and compared. In addition, the dielectric properties and electrical conductivity of the two were also investigated. The heat transport phenomenon of h-BN/epoxy and r-GO/epoxy nanocomposites were investigated using the transient plane source (HOT DISK) technique at room temperature. The h-BN/epoxy nanocomposites exhibited a higher thermal transport than the r-GO/epoxy nanocomposites. A high TC of ~ 2.6 W/mK and a high TD of ~ 9 mm2/s were observed at a h-BN loading of 2 vol% in the nanocomposite. The TC and TD values were ~ 33% and ~ 119% higher than r-GO/epoxy nanocomposite. The relative dielectric permittivity \({(\varepsilon }_{r})\) and loss (δ) was observed to be higher for r-GO/epoxy nanocomposite when compared to h-BN/epoxy nanocomposites. High relative dielectric permittivity of ~ 7.5 and loss of ~ 0.07 was obtained at a r-GO loading of ~ 2.2 vol% in the nanocomposite. Further, both nanocomposites retained a high electrical resistance. The study indicates h-BN/epoxy nanocomposite to hold significant potential for heat management in electronic applications.



中文翻译:

六方氮化硼和还原氧化石墨烯/环氧树脂纳米复合材料热电传输特性的瞬态平面源技术和阻抗谱对比研究

在研究范围内,研究并比较了六方氮化硼 (h-BN) 和还原石墨烯 (r-GO) 基环氧纳米复合材料的热导率 (TC) 和热扩散率 (TD)。此外,还研究了两者的介电性能和电导率。使用瞬态平面源(HOT DISK)技术在室温下研究了 h-BN/环氧树脂和 r-GO/环氧树脂纳米复合材料的热传输现象。h-BN/环氧树脂纳米复合材料表现出比 r-GO/环氧树脂纳米复合材料更高的热传输。在纳米复合材料中 h-BN 负载量为 2 vol% 时,观察到~ 2.6 W/mK 的高 TC 和 ~ 9 mm 2 /s的高 TD 。TC 和 TD 值比 r-GO/环氧树脂纳米复合材料高约 33% 和约 119%。相对介电常数与 h-BN/环氧树脂纳米复合材料相比,r-GO/环氧树脂纳米复合材料的\({(\varepsilon }_{r})\)和损失 ( δ ) 更高。在纳米复合材料中以~2.2 vol% 的 r-GO 负载量获得~7.5 的高相对介电常数和~0.07 的损耗。此外,两种纳米复合材料都保持高电阻。该研究表明 h-BN/环氧树脂纳米复合材料在电子应用中的热管理方面具有巨大的潜力。

更新日期:2021-09-15
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