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A Novel Benzimidazole-Based Chemosensor for Fluorometric Determination of Zinc Ions
Journal of Fluorescence ( IF 2.6 ) Pub Date : 2021-09-14 , DOI: 10.1007/s10895-021-02818-w
Ersin Orhan 1 , Ece Ergun 2 , Koray Şarkaya 3 , Ümit Ergun 1
Affiliation  

A simple and novel Schiff base chemosensor (BMHM) based on benzimidazole was synthesized. In ethanol–water (1:1, v/v) medium on varying concentrations of Zn2+ chemosensor exhibited a strong and quick turn on fluorescence response. The Zn2+ recognition was based on the Chelation–enhanced fluorescence effect. The binding constant and limit of detection for BMHM-Zn2+ complexation were estimated to be 7.99 × 104 M−1 and 0.148 µM, respectively. The extreme fluorescent enhancement caused by Zn2+ binding in chemosensor BMHM occurred at a pH range of 6–7. The practical use of chemosensor BMHM was tested by determination of Zn2+ in real water samples and comparing the results with the data obtained using high resolution inductively coupled plasma mass spectrometry.



中文翻译:

一种用于锌离子荧光测定的新型苯并咪唑基化学传感器

合成了一种基于苯并咪唑的简单而新颖的席夫碱化学传感器(BMHM)。在乙醇-水 (1:1, v/v) 介质中,不同浓度的 Zn 2+化学传感器表现出强烈而快速的荧光响应。Zn 2+识别基于螯合增强的荧光效应。BMHM-Zn 2+络合的结合常数和检测限估计分别为7.99 × 104 M -1和0.148 µM。由化学传感器 BMHM 中的 Zn 2+结合引起的极端荧光增强发生在 6-7 的 pH 范围内。通过测定Zn 2+测试化学传感器BMHM的实际应用 在实际水样中,并将结果与​​使用高分辨率电感耦合等离子体质谱法获得的数据进行比较。

更新日期:2021-09-15
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