Peptide-Based Supramolecular Systems Chemistry,Chemical Reviews

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Peptide-Based Supramolecular Systems Chemistry
Chemical Reviews ( IF 51.4 ) Pub Date : 2021-09-14 , DOI: 10.1021/acs.chemrev.1c00089
Fahmeed Sheehan _{1,

2,

3} , Deborah Sementa ₁ , Ankit Jain ₁ , Mohit Kumar _{1,

4} , Mona Tayarani-Najjaran _{1,

2,

3} , Daniela Kroiss _{1,

2,

5} , Rein V Ulijn _{1,

2,

3,

5}

Affiliation

Peptide-based supramolecular systems chemistry seeks to mimic the ability of life forms to use conserved sets of building blocks and chemical reactions to achieve a bewildering array of functions. Building on the design principles for short peptide-based nanomaterials with properties, such as self-assembly, recognition, catalysis, and actuation, are increasingly available. Peptide-based supramolecular systems chemistry is starting to address the far greater challenge of systems-level design to access complex functions that emerge when multiple reactions and interactions are coordinated and integrated. We discuss key features relevant to systems-level design, including regulating supramolecular order and disorder, development of active and adaptive systems by considering kinetic and thermodynamic design aspects and combinatorial dynamic covalent and noncovalent interactions. Finally, we discuss how structural and dynamic design concepts, including preorganization and induced fit, are critical to the ability to develop adaptive materials with adaptive and tunable photonic, electronic, and catalytic properties. Finally, we highlight examples where multiple features are combined, resulting in chemical systems and materials that display adaptive properties that cannot be achieved without this level of integration.

中文翻译：

基于肽的超分子系统化学

基于肽的超分子系统化学试图模仿生命形式的能力，以使用保守的构建块组和化学反应来实现一系列令人眼花缭乱的功能。基于具有自组装、识别、催化和驱动等特性的短肽基纳米材料的设计原则，越来越多地可用。基于肽的超分子系统化学开始解决系统级设计的更大挑战，以获取在协调和整合多个反应和相互作用时出现的复杂功能。我们讨论了与系统级设计相关的关键特征，包括调节超分子有序和无序，通过考虑动力学和热力学设计方面以及组合动态共价和非共价相互作用来开发主动和自适应系统。最后，我们讨论了结构和动态设计概念，包括预组织和诱导拟合，对于开发具有自适应和可调光子、电子和催化特性的自适应材料的能力至关重要。最后，我们重点介绍了多个特征组合在一起的示例，从而产生了具有自适应特性的化学系统和材料，如果没有这种集成水平，这些特性将无法实现。和催化性能。最后，我们重点介绍了多个特征组合在一起的示例，从而产生了具有自适应特性的化学系统和材料，如果没有这种集成水平，这些特性将无法实现。和催化性能。最后，我们重点介绍了多个特征组合在一起的示例，从而产生了具有自适应特性的化学系统和材料，如果没有这种集成水平，这些特性将无法实现。

更新日期：2021-09-14

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