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A ring of grids: a giant spin-crossover cluster
Chemical Communications ( IF 4.3 ) Pub Date : 2021-09-13 , DOI: 10.1039/d1cc04346c
Takuya Shiga 1 , Minami Tachibana 1 , Hajime Sagayama 2 , Reiji Kumai 2 , Graham N Newton 3 , Hiroki Oshio 1, 4 , Masayuki Nihei 1
Affiliation  

Mononuclear and icosanuclear spin-crossover complexes, [FeII(HL)2](BF4)2 (1) and [FeII20(L)24](BF4)16 (2), were synthesized using an asymmetric multidentate ligand (HL). 1 has a bis-chelate structure with two protonated ligands, while 2 has a ring-shape structure comprising four [2 × 2] grid moieties and four mononuclear units.

中文翻译:

一圈网格:一个巨大的自旋交叉集群

使用不对称多齿配体合成了单核和二十核自旋交叉复合物 [Fe II (HL) 2 ](BF 4 ) 2 ( 1 ) 和 [Fe II 20 (L) 24 ](BF 4 ) 16 ( 2 ) (HL)。1具有带有两个质子化配体的双螯合物结构,而2具有包含四个 [2 × 2] 网格部分和四个单核单元的环状结构。
更新日期:2021-09-14
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