Chiral Indoline-2-carboxylic Acid Enables Highly Enantioselective Catellani-type Annulation with 4-(Bromomethyl)cyclohexanone,Angewandte Chemie International Edition

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Chiral Indoline-2-carboxylic Acid Enables Highly Enantioselective Catellani-type Annulation with 4-(Bromomethyl)cyclohexanone
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-09-14 , DOI: 10.1002/anie.202109771
Xin-Meng Chen ₁ , Ling Zhu ₁ , Dian-Feng Chen ₁ , Liu-Zhu Gong ₁

Affiliation

Chiral indoline-2-carboxylic acid enables a highly enantioselective Catellani-type annulation of (hetero)aryl iodides, alkenyl triflate and conjugated vinyl iodides with 4-(bromomethyl)cyclohexanone, directly assembling a diverse range of chiral all-carbon bridged ring systems.