Manganese-catalyzed amination reactions: An overview,Applied Organometallic Chemistry

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Manganese-catalyzed amination reactions: An overview
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2021-09-12 , DOI: 10.1002/aoc.6421
Rahim Farzana ₁ , Sankaran Radhika ₁ , Salim Saranya ₁ , Gopinathan Anilkumar _{1,

2,

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Affiliation

As the nitrogen-containing compounds have broad scope in biological, pharmaceutical, drug delivery, and material science, the C–N bond formation has vital role in synthetic chemistry. To provide a path for the inclusion of nitrogen in organic molecules, a facile establishment of C–N bonds is crucial. Manganese being inexpensive, nontoxic, and earth abundant is found to be a perfect catalyst to carry out amination, instead of using harsh reaction conditions or toxic metal catalysts. Herein, we discuss the manganese-catalyzed amination reactions focusing on various manganese based catalysts for the C–N bond formation and covers the literature until 2020.

中文翻译：

锰催化的胺化反应：概述

由于含氮化合物在生物、制药、药物输送和材料科学领域具有广泛的应用范围，因此 C-N 键的形成在合成化学中具有重要作用。为了提供将氮包含在有机分子中的途径，C-N 键的轻松建立至关重要。锰便宜、无毒且富含地球资源，被发现是进行胺化的完美催化剂，而不是使用苛刻的反应条件或有毒金属催化剂。在此，我们讨论了锰催化的胺化反应，重点是用于形成 C-N 键的各种锰基催化剂，并涵盖了 2020 年之前的文献。

更新日期：2021-09-12

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