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Nano Ni/g-C3N4 Photocatalyzed Aerobic Oxidative Coupling Reaction toward Alkyl Aryl Ketones Derivatives under Visible Light Irradiation
ChemistrySelect ( IF 2.1 ) Pub Date : 2021-09-12 , DOI: 10.1002/slct.202102062
Mona Hosseini‐Sarvari 1 , Zahra Akrami 1
Affiliation  

In the present study, the synthesis of a group of carbonyl compounds that are widely used in the chemical and pharmaceutical industries was prepared under mild and safe conditions. We developed a new method based on the nickel/carbon nitride (Ni/g-C3N4) dual photocatalytic system to synthesize ketones without using expensive oxidants and heating. This article describes the oxidative coupling reactions between tertiary amines and aryl halides resulting in the production of natural aryl alkyl ketones. It should be noted that all these reactions were carried out using visible light, green solvents under eco-friendly, one-pot conditions, an air atmosphere, at room temperature, without the use of any oxidant.

中文翻译:

可见光照射下纳米Ni/g-C3N4光催化烷基芳基酮衍生物的好氧氧化偶联反应

在本研究中,在温和安全的条件下合成了一组广泛用于化学和制药行业的羰基化合物。我们开发了一种基于镍/氮化碳 (Ni/gC 3 N 4 ) 双光催化体系的新方法,无需使用昂贵的氧化剂和加热即可合成酮。本文描述了叔胺和芳基卤化物之间的氧化偶联反应,从而产生了天然的芳基烷基酮。应该指出的是,所有这些反应都是在环境友好、一锅条件、空气气氛、室温下使用可见光、绿色溶剂进行的,没有使用任何氧化剂。
更新日期:2021-09-13
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