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Amplifying the reactivity of BODIPY photoremovable protecting groups
Chemical Communications ( IF 4.9 ) Pub Date : 2021-09-07 , DOI: 10.1039/d1cc04457e
Matthew J Goodwin 1 , Xinzi Zhang 1 , Tayli B Shekleton 1 , Delaney A Kirr 1 , Henry C Hannon 1 , Elizabeth J Harbron 1
Affiliation  

Conjugated polymer nanoparticles (CPNs or Pdots) are used to sensitize the photorelease reaction of a BODIPY photoremovable protecting group. Sensitization yields effective values of ελΦpr – the product of the extinction coefficient at the irradiation wavelength and the photorelease quantum yield – that are more than 60-fold greater than those measured upon direct excitation.

中文翻译:

放大 BODIPY 光可去除保护基团的反应性

共轭聚合物纳米粒子(CPN 或 Pdot)用于敏化 BODIPY 光可去除保护基团的光释放反应。敏化产生ε λ Φ pr 的有效值——辐照波长处的消光系数与光释放量子产率的乘积——比直接激发时测量的值高 60 倍以上。
更新日期:2021-09-13
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