Polymeric Blatter's Radical via CuAAC and ROMP,Macromolecular Chemistry and Physics

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Polymeric Blatter's Radical via CuAAC and ROMP
Macromolecular Chemistry and Physics ( IF 2.5 ) Pub Date : 2021-09-12 , DOI: 10.1002/macp.202100194
Adrian Saal _{1,

2} , Christian Friebe _{1,

2} , Ulrich S. Schubert _{1,

2}

Affiliation

A Blatter radical-containing polymer backbone is synthesized via copper-catalyzed azide-alkyne cycloaddition (CuAAC) and consecutive ring-opening metathesis polymerization. For this, an alkyne-functionalized Blatter radical is synthesized and used for the described CuAAC, yielding a polymerizable derivative of the radical. The resulting polymer is electrochemically investigated in cyclic voltammetry experiments, paving the way for the possible utilization of triazinyl radicals in all-organic polymer batteries. Furthermore, the simple modification of the alkyne bond makes further derivatization easily accessible.

中文翻译：

通过 CuAAC 和 ROMP 的聚合物布拉特自由基

通过铜催化的叠氮化物-炔环加成 (CuAAC) 和连续开环复分解聚合合成了含有布拉特自由基的聚合物主链。为此，合成了炔官能化的布拉特自由基并将其用于所描述的 CuAAC，产生自由基的可聚合衍生物。在循环伏安法实验中对所得聚合物进行电化学研究，为三嗪基在全有机聚合物电池中的可能利用铺平了道路。此外，炔键的简单修饰使得进一步衍生化变得容易。

更新日期：2021-10-07

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