Abstract

New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF]_n (I), [Mg(pQ)·2DMAA]_n (II), and [Mg(pQ)·2(NMP)]_n (III) (pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion) are synthesized by the solvothermal method in different solvents (N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMAA), and N-methyl-2-pyrrolidone (NMP)). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files CCDC nos. 2058147 (I) and 2058148 (II)). The spectral characteristics and thermal stability of the synthesized metal−organic frameworks are studied.

中文翻译：

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基于 2,5-二羟基-3,6-二叔丁基对苯醌的镁金属有机骨架

摘要

镁[Mg(pQ)·2DMF] _n ( I )、[Mg(pQ)·2DMAA] _n ( II )和[Mg(pQ)·2(NMP)] _n ( III ) (pQ 是 2,5-dihydroxy-3,6- di - tert - butyl - para - benzoquinone dianion) 在不同溶剂 ( N , N-二甲基甲酰胺 (DMF), N , N -二甲基乙酰胺（DMAA）和N-甲基-2-吡咯烷酮（NMP））。化合物I和III的晶体结构通过 X 射线结构分析（CIF 文件 CCDC 编号 2058147 ( I ) 和 2058148 ( II )）确定。研究了合成的金属有机骨架的光谱特性和热稳定性。