当前位置: X-MOL 学术Russ. J. Coord. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Metal–Organic Frameworks of Magnesium Based on 2,5-Dihydroxy-3,6-di-tert-butyl-para-benzoquinone
Russian Journal of Coordination Chemistry ( IF 1.1 ) Pub Date : 2021-09-10 , DOI: 10.1134/s1070328421090086
O. Yu. Trofimova 1 , I. V. Ershova 1 , A. V. Maleeva 1 , A. V. Piskunov 1 , I. A. Yakushev 2, 3 , P. V. Dorovatovskii 3 , R. R. Aisin 4
Affiliation  

Abstract

New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF]n (I), [Mg(pQ)·2DMAA]n (II), and [Mg(pQ)·2(NMP)]n (III) (pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion) are synthesized by the solvothermal method in different solvents (N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMAA), and N-methyl-2-pyrrolidone (NMP)). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files CCDC nos. 2058147 (I) and 2058148 (II)). The spectral characteristics and thermal stability of the synthesized metal−organic frameworks are studied.



中文翻译:

基于 2,5-二羟基-3,6-二叔丁基对苯醌的镁金属有机骨架

摘要

镁[Mg(pQ)·2DMF] n ( I )、[Mg(pQ)·2DMAA] n ( II )和[Mg(pQ)·2(NMP)] n ( III ) (pQ 是 2,5-dihydroxy-3,6- di - tert - butyl - para - benzoquinone dianion) 在不同溶剂 ( N , N-二甲基甲酰胺 (DMF), N , N -二甲基乙酰胺(DMAA)和N-甲基-2-吡咯烷酮(NMP))。化合物IIII的晶体结构通过 X 射线结构分析(CIF 文件 CCDC 编号 2058147 ( I ) 和 2058148 ( II ))确定。研究了合成的金属有机骨架的光谱特性和热稳定性。

更新日期:2021-09-12
down
wechat
bug