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Elastic moduli and theoretical estimations of physical properties of Ge3Se7–As2Te3
Current Applied Physics ( IF 2.4 ) Pub Date : 2021-09-10 , DOI: 10.1016/j.cap.2021.08.013
A. El-Denglawey 1 , A. Dahshan 2, 3 , K.A. Aly 4, 5 , Y.B. Saddeek 5, 6
Affiliation  

The Bulk (100-x)Ge3Se7 - (x)As2Te3 (0 ≤ x ≤ 30) glassy alloys were prepared using the melt quenching technique. The elastic moduli (Bulk (K), Micro-hardness (H), Young (Y)), and Poisson's ratio (Pr) of the prepared glasses have been determined using the measured values of the ultrasonic velocities and density (ρ). Values of ρ were measured, then the molar volume (Vm) was estimated theoretically. The DSC thermograms are used to determine the glass transition temperature (Tg). The thermal evaporation method was used to prepare the (100-x)Ge3Se7- (x)As2Te3 (0 ≤ x ≤ 30) thin films under a vacuum of about 10−4Pa. The absorbance (A) of the films in the spectral range from 0.45 to 0.85 μm has been measured, then the absorption coefficient (α) and energy gap (Eg) were determined. The Chemical Bond Approach (CBA) has been used successfully to estimate theoretically various physical and structural characteristics of the studied system. Theoretical values of Eg and Tg have been obtained using different methods. The results proved a remarkable agreement between the theoretical and experimental values for both the Eg and Tg. The Eg values decreased from 2.1 to 1.73 eV by increasing the As2Te3 content from 0 to 30 at. %. Therefore, these compounds can be used as an absorbing layer for electromagnetic radiation in photovoltaic devices and sensors.



中文翻译:

Ge3Se7–As2Te3 的弹性模量和物理性质的理论估计

使用熔融淬火技术制备块状 (100-x)Ge 3 Se 7 - (x)As 2 Te 3 (0 ≤ x ≤ 30) 玻璃态合金。所制备玻璃的弹性模量(体积 ( K )、显微硬度 ( H )、杨氏 ( Y ))和泊松比 ( P r ) 已使用超声波速度和密度 ( ρ )的测量值确定。测量 ρ 值,然后从理论上估计摩尔体积 ( V m )。DSC 热谱图用于确定玻璃化转变温度 ( T g)。采用热蒸发法在约10 -4 Pa的真空下制备(100-x)Ge 3 Se 7 - (x)As 2 Te 3 (0 ≤ x ≤ 30)薄膜。吸光度(A)测量了光谱范围从 0.45 到 0.85 μm 的薄膜,然后确定了吸收系数 (α) 和能隙 ( E g )。化学键法 (CBA) 已成功用于从理论上估计所研究系统的各种物理和结构特征。E gT g 的理论值已使用不同的方法获得。结果证明E gT g的理论值和实验值之间具有显着的一致性。通过将 As 2 Te 3含量从 0 at 增加到 30 at ,E g值从 2.1 eV 降低到 1.73 eV 。%。因此,这些化合物可用作光伏器件和传感器中电磁辐射的吸收层。

更新日期:2021-09-14
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