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Highly Emissive Cerium(III) Thiocyanate Complexes Reevaluated Using a Silane-Treated Quartz Cell
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2021-09-12 , DOI: 10.1002/ejic.202100626
Yusuke Kuramochi 1 , Kotaro Ohminato 2 , Shunsuke Sayama 2 , Akiharu Satake 2
Affiliation  

A silane treatment on the quartz cell which prevents the formation of the Ce(IV) species and the titration experiments under an Ar atmosphere enable correct evaluation of the emission properties of the Ce(III) thiocyanate complexes, in which the emission quantum yield Φem is estimated to be 91 % in acetonitrile for Ce(SCN)3.
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中文翻译:

使用经硅烷处理的石英电池重新评估高发射性硫氰酸铈 (III) 配合物

石英池上的硅烷处理可防止 Ce(IV) 物种的形成和 Ar 气氛下的滴定实验能够正确评估 Ce(III) 硫氰酸盐配合物的发射特性,其中发射量子产率 Φ em Ce(SCN) 3 的乙腈含量估计为 91% 。
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更新日期:2021-11-02
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