INQUINOA (CONICET-UNT), Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, Ayacucho 471, (4000) San Miguel de Tucumán, Argentina.
Department of Chemistry, Yale University, P.O. Box 208107, New Haven, CT 06520, USA.
Department of Chemistry, The College of New Jersey, Ewing, NJ 08628, USA. (as of 7/1/2021).
Department of Chemistry, University of Washington, Seattle, Washington 98195-1700, USA.
The Front Cover shows the transfer of two electrons and two protons, and how they help each other move along the bridge. This is a picture of what we have seen in this Ru-bisamido model complex where the potential inversion favors this multi-redox reactivity. The stabilization produced by Ru−N bonding stabilizes the full transfer of two electrons which are accompanied by protons. This is a step in our learning of this complex four-particle transfer process. These studies bring tools to further understand the increased complexity of multi-PCET reactions. More information can be found in the Full Paper by M. Cattaneo and co-workers.
中文翻译：
封面：钌 (II)-胺和钌 (IV)-氨基配合物的多 PCET 反应性的结构、电子和热化学偏好（Eur. J. Inorg. Chem. 39/2021）
封面展示了两个电子和两个质子的转移，以及它们如何相互帮助沿着桥移动。这是我们在这个 Ru-bisamido 模型复合体中看到的图片，其中潜在的反转有利于这种多氧化还原反应。Ru-N 键合产生的稳定性稳定了伴随质子的两个电子的完全转移。这是我们学习这个复杂的四粒子转移过程的一个步骤。这些研究为进一步了解多 PCET 反应的复杂性增加提供了工具。更多信息可以在 M. Cattaneo 及其同事的全文中找到。
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