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Synthesis of a library of SCF2CO2Et reagents: An access to original (ethoxycarbonyl)difluoromethylthioesters
Tetrahedron ( IF 2.1 ) Pub Date : 2021-09-10 , DOI: 10.1016/j.tet.2021.132446 Fabien Petit-Cancelier 1 , Samuel Couve-Bonnaire 1 , Tatiana Besset 1
中文翻译：
SCF2CO2Et 试剂库的合成：获得原始（乙氧羰基）二氟甲基硫酯
更新日期：2021-09-24
Tetrahedron ( IF 2.1 ) Pub Date : 2021-09-10 , DOI: 10.1016/j.tet.2021.132446 Fabien Petit-Cancelier 1 , Samuel Couve-Bonnaire 1 , Tatiana Besset 1
Affiliation
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A library of original and shelf-stable reagents, source of the (ethoxycarbonyl)difluoromethylthio group, is reported. These reagents are applied to the functionalization of a large panel of aldehydes via a transition metal-free protocol under mild reaction conditions. This approach offers an efficient access to valuable difluoromethylthioester derivatives.
中文翻译：
SCF2CO2Et 试剂库的合成：获得原始（乙氧羰基）二氟甲基硫酯
报告了原始和货架稳定试剂库，（乙氧羰基）二氟甲硫基的来源。这些试剂在温和的反应条件下通过无过渡金属的协议应用于大量醛的功能化。这种方法提供了获得有价值的二氟甲基硫酯衍生物的有效途径。
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