Journal of Electroceramics ( IF 1.7 ) Pub Date : 2021-09-10 , DOI: 10.1007/s10832-021-00247-6 Lay-Gaik Teoh , Hao-Long Chen , Sean Wu , Chia-Rong Chang , Yee-Shin Chang
The luminescent properties of Pr3+ ion-doped t-type LaVO4 phosphor synthesized by the hydrothermal method were investigated. The XRD results shows that the optimum conditions for preparing t-type LaVO4 are 180 oC, 16 h. These particles are homogeneous distribution with uniform particle sizes for various Pr3+ ion concentrations, but the particle sizes seem to be increased with increasing Pr3+ ion contents. For Pr3+ ion-doped m-type and t-type LaVO4 phosphor, the absorption and excitation behavior are almost the same, but there is an obviously difference for emission behavior. The main emission peak is from the 1D2→3H4 transition for Pr3+ ion-doped t-type LaVO4 phosphor. The Commission International de I’Edairage chromaticity coordinates shifted from blue region to white region, and then shift to light-blue region. A single white light emitting phosphor can be obtained if the Pr3+ ion concentration is appropriate.
中文翻译:
水热法制备Pr3+离子掺杂t-锆石型LaVO4的特性
研究了水热法合成的Pr 3+离子掺杂t型LaVO 4荧光粉的发光性能。XRD结果表明,制备t型LaVO 4的最佳条件是180 o C,16 h。对于不同的Pr 3+离子浓度,这些颗粒具有均匀的粒径分布,但粒径似乎随着Pr 3+离子含量的增加而增加。对于Pr 3+离子掺杂的m型和t型LaVO 4荧光粉,吸收和激发行为几乎相同,但发射行为存在明显差异。主要发射峰来自1Pr 3+离子掺杂的t型LaVO 4磷光体的D 2 → 3 H 4跃迁。Commission International de I'Edairage 色度坐标从蓝色区域转移到白色区域,然后转移到浅蓝色区域。如果Pr 3+离子浓度合适,可以获得单一的白色发光磷光体。