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Tuning the interfacial electronic transitions of bi-dimensional nanocomposites (pGO/ZnO) towards photocatalytic degradation and energy application
Environmental Research ( IF 7.7 ) Pub Date : 2021-09-10 , DOI: 10.1016/j.envres.2021.112050
Shiva Kumar Arumugasamy 1 , Shanmugam Ramakrishnan 2 , Dong Jin Yoo 3 , Saravanan Govindaraju 1 , Kyusik Yun 1
Affiliation  

The two-dimensional carbonaceous nanocomposites tend to have extreme capacitance and catalysis activity because of their surface tunability of oxygenated moieties aiding in photocatalytic degradation. Herewith, we performed microwave-assisted alkaline treatment of graphene oxide sheets to attain defective sites on the graphitic surface by altering microwave parameters. The synergism of zinc oxide (ZnO) on the graphitic surface impacts electronic transitions paving paths for vacant oxygen sites to promote photocatalytic degradation and catalytic activity. The photocatalytic efficiency of the synthesized material for the degradation of rhodamine B (RhB) because of its susceptibility in industrial effluents, and the degradation rate was estimated to be around 87.5% within a short span of 30 min by utilizing UV irradiation. Concomitantly, the pGO/ZnO coated substrate exhibits a specific capacity of 561.7 mAh/g and incredible coulombic efficiency illustrating pseudocapacitive nature. Furthermore, on subjecting the composite modified electrode to oxygen evolution catalysis due to the vacant sites located at the lattice edges attributing to the d-d coulombic interaction within the local electron clouds possessing a low overpotential of 205 mV with a Tafel slope of 84 mV/dec. This modest approach boosts an eco-friendly composite to develop photocatalytic degradability and bifunctional catalytic activity for futuristic necessity.



中文翻译:

调整二维纳米复合材料(pGO/ZnO)的界面电子跃迁以实现光催化降解和能量应用

二维碳质纳米复合材料往往具有极高的电容和催化活性,因为它们的含氧部分的表面可调性有助于光催化降解。因此,我们对氧化石墨烯片进行微波辅助碱处理,通过改变微波参数来获得石墨表面的缺陷位点。氧化锌(ZnO)在石墨表面的协同作用会影响电子跃迁,为空位氧位点铺平道路,以促进光催化降解和催化活性。合成材料对罗丹明 B (RhB) 的降解的光催化效率由于其在工业废水中的敏感性,利用紫外线照射在短短 30 分钟内估计降解率约为 87.5%。同时,pGO/ZnO 涂层基板表现出 561.7 mAh/g 的比容量和令人难以置信的库仑效率,说明了赝电容性质。此外,由于位于晶格边缘的空位归因于局部电子云内的 dd 库仑相互作用,对复合修饰电极进行析氧催化,具有 205 mV 的低过电位和 84 mV/dec 的塔菲尔斜率。这种适度的方法促进了环保复合材料的发展,以发展光催化降解性和双功能催化活性,以满足未来的需要。由于位于晶格边缘的空位归因于局部电子云内的dd库仑相互作用,使复合修饰电极经受析氧催化,该电子云具有205 mV的低过电位和84 mV / dec的Tafel斜率。这种适度的方法促进了环保复合材料的发展,以发展光催化降解性和双功能催化活性,以满足未来的需要。由于位于晶格边缘的空位归因于局部电子云内的dd库仑相互作用,使复合修饰电极经受析氧催化,该电子云具有205 mV的低过电位和84 mV / dec的Tafel斜率。这种适度的方法促进了环保复合材料的发展,以发展光催化降解性和双功能催化活性,以满足未来的需要。

更新日期:2021-09-17
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