当前位置:
X-MOL 学术
›
Eur. J. Org. Chem.
›
论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Unprecedented Reversal of Regioselectivity during Methanolysis and an Interception of Curtius Rearrangement
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-09 , DOI: 10.1002/ejoc.202101056 Mihir Mandal 1 , Alexei V. Buevich 2 , Hongwu Wang 2 , Andrew Brunskill 2 , Peter Orth 2 , John P. Caldwell 2 , Xiaoxiang Liu 2 , Robert Mazzola 2 , Jared Cumming 2 , Brian McKittrick 2 , Johnny Zhu 2 , Andrew Stamford 2
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-09 , DOI: 10.1002/ejoc.202101056 Mihir Mandal 1 , Alexei V. Buevich 2 , Hongwu Wang 2 , Andrew Brunskill 2 , Peter Orth 2 , John P. Caldwell 2 , Xiaoxiang Liu 2 , Robert Mazzola 2 , Jared Cumming 2 , Brian McKittrick 2 , Johnny Zhu 2 , Andrew Stamford 2
Affiliation
Subtle changes of substitution pattern of fluorine in the phenyl moiety resulted in unexpected reversal of regioselectivity of methanolysis and interception of Curtius rearrangement of quaternary acids to their corresponding amines.
中文翻译:
甲醇分解过程中区域选择性的前所未有的逆转和 Curtius 重排的拦截
苯基部分中氟取代模式的细微变化导致甲醇分解的区域选择性的意外逆转和季酸库尔蒂斯重排为其相应胺的拦截。
更新日期:2021-09-27
中文翻译:
甲醇分解过程中区域选择性的前所未有的逆转和 Curtius 重排的拦截
苯基部分中氟取代模式的细微变化导致甲醇分解的区域选择性的意外逆转和季酸库尔蒂斯重排为其相应胺的拦截。