Orientational self-sorting: formation of structurally defined Pd4L8 and Pd6L12 cages from low-symmetry dipyridyl ligands,Chemical Communications

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Orientational self-sorting: formation of structurally defined Pd4L8 and Pd6L12 cages from low-symmetry dipyridyl ligands
Chemical Communications ( IF 4.3 ) Pub Date : 2021-09-10 , DOI: 10.1039/d1cc03828a
Ru-Jin Li ₁ , Adam Marcus ₂ , Farzaneh Fadaei-Tirani ₁ , Kay Severin ₁

Affiliation

Tetra- and hexanuclear coordination cages were obtained in reactions of [Pd(CH₃CN)₄](BF₄)₂ with low-symmetry dipyridyl ligands. In both cases, only one structurally defined complex was formed out of a vast pool of potential isomers.

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