The electrochemical reduction of a flexible Mn(II) salen-based metal–organic framework,Dalton Transactions

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The electrochemical reduction of a flexible Mn(II) salen-based metal–organic framework
Dalton Transactions ( IF 3.5 ) Pub Date : 2021-08-31 , DOI: 10.1039/d1dt02589a
Marcello B Solomon ₁ , Carol Hua ₂ , Bun Chan ₃ , Tamara L Church ₄ , Seth M Cohen ₅ , Clifford P Kubiak ₅ , Katrina A Jolliffe ₁ , Deanna M D'Alessandro ₁

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A new metal–organic framework (MOF) containing a Mn(II) salen complex (BET surface area = 967 ± 6 m² g⁻¹) undergoes a reversible crystalline-to-amorphous transformation. Experimental studies and computational calculations show that the MOF is stable to a one-electron reduction at more anodic potentials than the corresponding discrete complex.

中文翻译：

柔性Mn（II）Salen基金属有机骨架的电化学还原

一种含有 Mn( II ) salen 络合物（BET 表面积 = 967 ± 6 m ² g ^-1）的新金属有机骨架 (MOF ) 经历了可逆的晶体到非晶态转变。实验研究和计算计算表明，与相应的离散复合物相比，MOF 在更多阳极电位下对单电子还原是稳定的。

更新日期：2021-09-09

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