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Effect of erbium doping on phase composition, mechanical and thermal properties of ZrO2-based ceramics
Journal of Rare Earths ( IF 5.2 ) Pub Date : 2021-09-08 , DOI: 10.1016/j.jre.2021.09.005
Zheng Cao 1, 2 , Shengli An 1, 2, 3 , Xiwen Song 2, 3
Affiliation  

ErxTi0.1Zr0.9–xO2–1.5x (x = 0.04, 0.05, 0.06, 0.07, 0.08) ceramics were synthesized by a solid-state reaction method. The influence of the Er3+ addition on the phase composition, Vickers hardness, fracture toughness, and thermal conductivity of this ceramic material was investigated. The X-ray diffraction results reveal that the c-ZrO2 content increases from 1.85 vol% to 33.89 vol%, and the percentage of t-ZrO2 decreases from 98.15 vol% to 66.11 vol% with the increase in Er3+ content from 4 mol% to 8 mol%. Moreover, the addition of Er3+ is beneficial to the volume expansion of the unit cell. At the same time, the incorporation of Er3+ weakens the coordination of oxygen ions around the metal cations, resulting in a corresponding decrease in the tetragonality of the t-ZrO2. The Vickers hardness and fracture toughness of the ErxTi0.1Zr0.9–xO2–1.5x ceramics show increasing and decreasing trends, respectively. The thermal conductivity has a significant decline due to point defects caused by the Er3+ doping. The 8ETZ ceramic exhibits the highest Vickers hardness (12.7 GPa), the lowest fracture toughness (7.6 MPa⋅m1/2), and the lowest average thermal conductivity (1.85 W/(m·K)) in the temperature range of 200–1000 °C. All of the above properties are higher than those of the Y2O3-stabilized ZrO2 ceramic.



中文翻译:

铒掺杂对ZrO2基陶瓷相组成、力学和热性能的影响

 采用固相反应法合成了Er x Ti 0.1 Zr 0.9– x O 2–1.5 x ( x = 0.04, 0.05, 0.06, 0.07, 0.08) 陶瓷。研究了添加Er 3+对该陶瓷材料的相组成、维氏硬度、断裂韧性和热导率的影响。X射线衍射结果表明,随着Er 3+含量的增加,c-ZrO 2的含量从1.85 vol%增加到33.89 vol%,t-ZrO 2的百分比从98.15 vol%降低到66.11 vol% 。 4 摩尔% 至 8 摩尔%。此外,添加 Er 3+有利于晶胞的体积膨胀。同时,Er 3+的掺入削弱了氧离子在金属阳离子周围的配位,导致t-ZrO 2的四方性相应降低。Er x Ti 0.1 Zr 0.9– x O 2–1.5 x陶瓷的维氏硬度和断裂韧性分别呈上升和下降趋势。由于Er 3+掺杂引起的点缺陷,热导率显着下降。8ETZ陶瓷的维氏硬度最高(12.7 GPa),断裂韧性最低(7.6 MPa·m 1/2),以及 200–1000 °C 温度范围内的最低平均热导率 (1.85 W/(m·K))。上述所有性能均高于Y 2 O 3稳定化ZrO 2陶瓷的性能。

更新日期:2021-09-08
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