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Syntheses of 1H-Indoles, Quinolines, and 6-Membered Aromatic N-Heterocycle-Fused Scaffolds via Palladium(II)-Catalyzed Aerobic Dehydrogenation under Alkoxide-Free Conditions
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2021-09-07 , DOI: 10.1002/asia.202100861
Hyung-Seok Yoo 1 , Yo-Sep Yang 1 , Soo Lim Kim 2 , Seung Hwan Son 1 , Yoon Hu Jang 2 , Jeong-Won Shin 2 , Nam-Jung Kim 1, 2
Affiliation  

An efficient palladium(II)-catalyzed aerobic dehydrogenation of saturated N-heterocycle-fused scaffolds was developed. This method provides aromatic N-heterocylces including indoles, quinolines, isoquinolines, and other 6-membered N-heterocycles in good to excellent yields without the need of alkoxides (for 48 examples, up to 99% yield).
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中文翻译:

在无醇盐条件下通过钯 (II) 催化需氧脱氢合成 1H-吲哚、喹啉和 6 元芳香族 N-杂环稠合支架

开发了一种高效的钯 (II) 催化的饱和N-杂环稠合支架的有氧脱氢反应。该方法无需醇盐即可提供芳香族N-杂环,包括吲哚、喹啉、异喹啉和其他 6 元N-杂环,产率良好至极好(对于 48 个实例,产率高达 99%)。
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更新日期:2021-11-03
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