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Study of kinetic and thermal decomposition from municipal solid waste pellets using model-fitting methods
IOP Conference Series: Materials Science and Engineering Pub Date : 2021-09-01 , DOI: 10.1088/1757-899x/1173/1/012033
S R H Siregar , D Nursani , M I B Setyawan , A Surjosatyo

Reaction rate model could be determined from kinetic characteristics. Kinetic and thermal decomposition of municipal solid waste (MSW) pellets, consist of organic material, plastic, paper and leaves, with tapioca flour as binder (0%, 3% and 6%) were studied in thermogravimetric analyzer from temperature 50C to 800C at heating rate 10 0C/min in N2 atmospheres. The kinetic parameter were determined by Model Fitting or Coats Redfern Methods with different kinetic reaction model. Results of this study have shown that MSW pellets in various binder has activation energy values 64.64 kJ/mol and 22.06 kJ/mol for 0%, 68.83 kJ/mol and 21.99 kJ/mol for 3%, and 69.29 kJ/mol and 22.62 kJ/mol for 6% at temperature ranges between 200C-400C and 400C-500C respectively in typical three dimensional diffusion (D3) mechanism kinetic reaction model.



中文翻译:

使用模型拟合方法研究城市固体废物颗粒的动力学和热分解

反应速率模型可以从动力学特性确定。城市固体废物 (MSW) 颗粒的动力学和热分解由有机材料、塑料、纸和树叶组成,以木薯粉为粘合剂(0%、3% 和 6%)在热重分析仪中从 50C 到 800C 的温度进行了研究在 N 2 中加热速率 10 0 C/min气氛。动力学参数通过模型拟合或 Coats Redfern 方法确定,具有不同的动力学反应模型。本研究结果表明,不同粘合剂中的 MSW 颗粒的活化能值为 64.64 kJ/mol 和 22.06 kJ/mol,0% 时为 68.83 kJ/mol 和 21.99 kJ/mol,3% 时为 69.29 kJ/mol 和 22.62 kJ在典型的三维扩散 (D3) 机制动力学反应模型中,在 200C-400C 和 400C-500C 之间的温度范围内,/mol 为 6%。

更新日期:2021-09-01
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