Palladium catalyzed selective amination of B(7)-H for synthesis of o-carborane fused isoquinolinones,Journal of Organometallic Chemistry

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Palladium catalyzed selective amination of B(7)-H for synthesis of o-carborane fused isoquinolinones
Journal of Organometallic Chemistry ( IF 2.1 ) Pub Date : 2021-09-05 , DOI: 10.1016/j.jorganchem.2021.122069
Ke Cao ₁ , Ji Wu _{1,

2} , Cai-Yan Zhang ₁ , Li-Fang Ding ₁ , Junxiao Yang ₁

Affiliation

A palladium catalyzed intramolecular amination of B(7)-H for synthesis of o-carborane fused isoquinolinones has been developed. Kinds of o-carborane fused isoquinolinones decorated with active groups have been synthesized with good to excellent yields. A plausible mechanism involving palladium catalyzed electrophilic B-H activation/amination was proposed.

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