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Effect of plasma atmosphere on the oxygen transport of mixed ionic and electronic conducting hollow fiber membranes
Journal of Industrial and Engineering Chemistry ( IF 5.9 ) Pub Date : 2021-09-06 , DOI: 10.1016/j.jiec.2021.08.044
F. Buck 1, 2 , K. Wiegers 3 , A. Schulz 3 , T. Schiestel 1
Affiliation  

Perovskite hollow fibers have been used to extract oxygen from different oxygen containing plasmas. The influence of the working length and the temperature on the oxygen transport of (La0.6Ca0.4)(Co0.8Fe0.2)O3-δ (LCCF) hollow fiber membranes in an air and a CO2 plasma were investigated and compared with a conventional electrically heated oven system at a similar temperature. High-quality LCCF hollow fiber membranes were prepared via phase inversion spinning and sintering. In the CO2 plasma, the feasibility of the oxygen extraction due to the CO2 splitting according to CO2 CO + ½ O2 was studied. For an active membrane length of 0.5 cm, oxygen permeation values of 17.27 ml min−1 cm−2 in an air plasma at 0.67 kW and 4.97 ml min−1 cm−2 in a CO2 plasma at 1 kW were reached.



中文翻译:

等离子气氛对离子和电子混合导电中空纤维膜氧传输的影响

钙钛矿中空纤维已被用于从不同的含氧等离子体中提取氧气。研究了工作长度和温度对 (La 0.6 Ca 0.4 )(Co 0.8 Fe 0.2 )O 3-δ (LCCF) 中空纤维膜在空气和 CO 2等离子体中氧传输的影响,并与传统的电加热烤箱系统在类似的温度。通过转相纺丝和烧结制备了高质量的LCCF中空纤维膜。在 CO 2等离子体中,由于根据 CO 2的 CO 2分裂,氧气提取的可行性 研究了 CO + 1/2 O 2。对于0.5cm的活性膜长度,在0.67kW的空气等离子体中达到17.27ml min -1 cm -2和在1kW的CO 2等离子体中4.97ml min -1 cm -2 的氧渗透值。

更新日期:2021-10-11
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