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Microscale δ34S heterogeneities in cold seep barite record variable methane flux off the Lofoten-Veståralen Continental Margin, Norway
Earth and Planetary Science Letters ( IF 4.8 ) Pub Date : 2021-09-06 , DOI: 10.1016/j.epsl.2021.117164
R. Seth Wood 1 , Aivo Lepland 2 , Ryan C. Ogliore 3 , Jennifer Houghton 1 , David A. Fike 1
Affiliation  

Authigenic carbonate and barite crusts were analyzed from recently discovered cold seeps on the Lofoten-Vesterålen (LV) continental slope, northern Norway. Carbonate phases in these crusts are methane-derived Mg-calcite and aragonite. Scanning electron microscopy (SEM) was used to petrographically characterize cold seep crusts, and secondary ion mass spectrometry (SIMS) was used to measure the microscale sulfur isotope composition (δ34S values) of authigenic barite. The mean δ34SBaSO4 value from SIMS spot analyses is 70‰ (n = 303), significantly elevated with respect to seawater sulfate (∼21‰). The δ34S values can vary more than 40‰ within individual barite aggregates (< 250 μm) and more than 50‰ within cm-scale samples. δ34SBaSO4 values in layered barite aggregates are most variable parallel to growth axes, with minimal variability in the perpendicular direction; fluctuations in δ34SBaSO4 values along growth axes are inferred to record temporal changes in sulfate distillation during barite precipitation. In layered barite aggregates, δ34SBaSO4 values frequently approach ∼90‰, but at these high δ34S values, barite dissolution features become increasingly prevalent and may reflect an upper limit for porewater 34SSO4 enrichment while maintaining barite saturation in this system. We suggest the primary forcing affecting sulfate distillation is varying activity of anaerobic oxidation of methane coupled to sulfate reduction (AOM-SR) due to temporal changes in cold seep methane flux. These findings provide the first semi-continuous geologic proxy for paleo-methane flux on the Lofoten-Vesterålen continental margin and suggest methane advection rates varied considerably over the course of carbonate-barite crust formation. In addition to systematic microscale changes in δ34SBaSO4 values, periodic intra-aggregate dissolution features indicate a dynamic seepage environment with two or more periods of enhanced methane flux in recent geological history.



中文翻译:

挪威 Lofoten-Veståralen 大陆边缘冷渗重晶石中的微尺度 δ34S 异质性记录变量甲烷通量

从最近在挪威北部 Lofoten-Vesterålen (LV) 大陆坡上发现的冷渗流中分析了自生碳酸盐和重晶石结壳。这些地壳中的碳酸盐相是甲烷衍生的镁方解石和文石。使用扫描电子显微镜 (SEM) 对冷渗结壳进行岩相学表征,并使用二次离子质谱法 (SIMS) 测量微尺度硫同位素组成。δ34S 值)的自生重晶石。均值δ34SIMS 现场分析的S BaSO4值为 70‰ (n = 303),相对于海水硫酸盐 (~21‰) 显着升高。这δ34S 值在单个重晶石聚集体 (< 250 μm) 内变化超过 40‰,在厘米级样品内变化超过 50‰。 δ34层状重晶石聚集体中的S BaSO4值在平行于生长轴的方向上变化最大,在垂直方向上的变化最小;波动δ34推断沿生长轴的S BaSO4值记录重晶石沉淀过程中硫酸盐蒸馏的时间变化。在层状重晶石聚集体中,δ34S BaSO4值经常接近 ~90‰,但在这些高δ34S 值、重晶石溶解特征变得越来越普遍,并且可能反映了孔隙水34 S SO4富集的上限,同时保持该系统中的重晶石饱和。我们认为影响硫酸盐蒸馏的主要强迫是由于冷渗甲烷通量的时间变化而导致的甲烷厌氧氧化与硫酸盐还原 (AOM-SR) 耦合的不同活动。这些发现为 Lofoten-Vesterålen 大陆边缘的古甲烷通量提供了第一个半连续地质代理,并表明甲烷平流率在碳酸盐-重晶石地壳形成过程中变化很大。除了系统性的微观变化δ34S BaSO4值、周期性的骨料内溶解特征表明在最近的地质历史中具有两个或更多个时期的甲烷通量增强的动态渗流环境。

更新日期:2021-09-06
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