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Molecular design strategies for high-performance organic electrochemical transistors
Journal of Polymer Science ( IF 3.9 ) Pub Date : 2021-09-05 , DOI: 10.1002/pol.20210503
Peiyun Li 1 , Ting Lei 1
Affiliation  

Organic electrochemical transistors (OECTs) utilize ion flow from the electrolyte to modulate the electrical conductivity of the whole bulk organic semiconductor channel. With the characteristic of mixed ionic-electronic conducting in the entire volume, OECTs exhibit high transconductance and act as good transducers, particularly in bioelectronics. To gain high-performance OECTs, developing novel high-performance polymeric semiconductors is important. In this article, operation principles, performance evaluations, and polymerization methods are first discussed. We then analyze the molecular design strategies for high-performance OECT materials and highlight the characteristics and effects of backbone design and side chain engineering. Finally, we discuss some neglected and unsolved issues and provide an outlook for the OECTs research and development.

中文翻译:

高性能有机电化学晶体管的分子设计策略

有机电化学晶体管 (OECT) 利用来自电解质的离子流来调节整个体有机半导体通道的电导率。凭借在整个体积中混合离子-电子传导的特性,OECT 表现出高跨导并充当良好的换能器,特别是在生物电子学中。为了获得高性能 OECT,开发新型高性能聚合物半导体非常重要。本文首先讨论了操作原理、性能评估和聚合方法。然后,我们分析了高性能 OECT 材料的分子设计策略,并强调了主链设计和侧链工程的特点和效果。最后,
更新日期:2021-09-05
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