Optical Materials ( IF 3.8 ) Pub Date : 2021-09-04 , DOI: 10.1016/j.optmat.2021.111477 Mei-Hong Liu 1 , Jia-Min Liu 1 , Feng Chen 1 , De-Long Zhang 1
Dependences of Judd-Ofelt (JO) intensity parameters Ωt (t = 2,4,6) and their relative ratios (Ω4/Ω2 and Ω6/Ω2) on overall changing factor (q) of integrated absorption bands of Er3+ have been studied theoretically. These dependences can help us to use relevant method to correctly extract Ωt of a powder material. The study was done by exemplifying the widely studied Er3+ system, which is doped into Gd3Ga5O12, LiNbO3 and SrGdGa3O7 bulk single-crystals and β-NaYF4 crystalline powder. The results show that the Ωt changes linearly with the overall changing factor q: Ωt = γtq + ξt. The linear feature changes from one material to another. The magnetic-dipole oscillator of the 1.5 μm transition results in non-zero nodal increment ξt and hence dramatical changes of the relative ratios Ω4/Ω2 and Ω6/Ω2 (with q) in smaller q region. The dramatical feature limits application of the relevant method for Ωt calibration of a luminescent powder. To get the precise Ωt values using the relevant method, the q value must be large enough. This can be realized by adopting a thin powder plate with a low Er3+ concentration for spectral measurement.
中文翻译:
Judd-Ofelt 参数对 Er3+ 积分吸收带整体变化因子的依赖性
Judd-Ofelt (JO) 强度参数 Ω t (t = 2,4,6) 及其相对比率(Ω 4 /Ω 2和Ω 6 /Ω 2)对积分吸收带的整体变化因子(q)的依赖性Er 3+已经在理论上进行了研究。这些相关性可以帮助我们使用相关方法正确提取粉末材料的Ω t。该研究以广泛研究的 Er 3+系统为例,该系统掺杂到 Gd 3 Ga 5 O 12、LiNbO 3和 SrGdGa 3 O 7 中块状单晶和β-NaYF 4结晶粉末。结果表明,Ω t随整体变化因子q呈线性变化:Ω t = γ t q + ξ t。线性特征从一种材料变为另一种材料。1.5 μm 跃迁的磁偶极子振荡器导致非零节点增量 ξ t,因此在较小的q区域中Ω 4 /Ω 2和 Ω 6 /Ω 2(与q)的相对比率发生显着变化。戏剧性的特征限制了相关方法对Ω t 的应用荧光粉的校准。要使用相关方法获得精确的Ω t值,q值必须足够大。这可以通过采用具有低Er 3+浓度的薄粉板进行光谱测量来实现。