当前位置: X-MOL 学术Org. Biomol. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Visible light-induced C–C bond cleavage in a multicomponent reaction cascade allowing acylations of sulfoximines with ketones
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2021-08-18 , DOI: 10.1039/d1ob01411k
Yongliang Tu 1 , Duo Zhang 1 , Peng Shi 1 , Chenyang Wang 1 , Ding Ma 1 , Carsten Bolm 1
Affiliation  

Visible light induces C–C-bond cleavage reactions of ketones, which can be utilized for N-acylations of sulfoximines. No (photo)catalyst is required, and the reactions occur at ambient temperature in air. The substrate scope is broad for both ketones and sulfoximines. For converting NH-sulfoximines, the presence of NBS is essential.

中文翻译:

多组分反应级联中可见光诱导的 C-C 键断裂,允许亚砜亚胺与酮的酰化

可见光诱导酮的 C-C-键裂解反应,可用于亚砜亚胺的N-酰化。不需要(光)催化剂,反应在空气中的环境温度下发生。酮和亚砜亚胺的底物范围很广。为了转化N H-亚砜亚胺,NBS 的存在是必不可少的。
更新日期:2021-09-06
down
wechat
bug