Inorganic Chemistry Communications ( IF 4.4 ) Pub Date : 2021-09-04 , DOI: 10.1016/j.inoche.2021.108873 Hu Zhao 1 , Mingqiang Li 1 , Ziren Fang 1 , Qingyun Su 1
As one of the most important elements in the halogen family, bromine has a theoretical specific capacity of 335 mAh g−1, which makes it a very suitable active material for rechargeable batteries. In this study, we use the superb Br- ion storage of MoS2 nano-flowers, which achieve high specific capacity (1 5 1 ) and excellent stability (more than 5000 cycles). Through a series of characterization analyses, it is proved bromine ions are intercalate in MoS2 during the charging process. During discharge, Br- deintercalates from MoS2 and moves to the anode. This reversible and stable chemical action provides feasibility for the intercalation/deintercalation of bromine-based batteries. There is no doubt that this research will provide researchers with new strategies for bromine-based batteries.
中文翻译:
二维材料二硫化钼纳米花的新型碱性水基衍生物可充电溴基电池
作为卤素族中最重要的元素之一,溴的理论比容量为 335 mAh g -1,这使其成为非常适合可充电电池的活性材料。在这项研究中,我们使用了MoS 2纳米花卓越的 Br -离子存储能力,实现了高比容量 (1 5 1 ) 和出色的稳定性(超过 5000 次循环)。通过一系列表征分析,证明在充电过程中溴离子嵌入MoS 2中。在放电期间,Br -从MoS 2脱嵌并移动到阳极。这种可逆且稳定的化学作用为溴基电池的嵌入/脱嵌提供了可行性。毫无疑问,这项研究将为研究人员提供溴基电池的新策略。