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Multi-isotopic (O, H, C, S, Sr, B, Li) characterization of waters in a low-enthalpy geothermal system in Havza (Samsun), Turkey
Geothermics ( IF 3.5 ) Pub Date : 2021-09-03 , DOI: 10.1016/j.geothermics.2021.102240
Esra Hatipoğlu Temizel 1 , Fatma Gültekin 1 , Arzu Fırat Ersoy 1 , Reyhan Kara Gülbay 1
Affiliation  

In this study, multi-isotopic (O, H, C, S, Sr, B, Li) compositions were used to perform geochemical characterization, determine the source and reservoir rocks, and explain the water-rock interaction mechanisms for geothermal fluids in the low-enthalpy Havza (Samsun) geothermal field (HGF) in Turkey. The geothermal water of Na-HCO3 water type has a wellhead temperature of 53°C, pH of nearly 7.7 and an EC value of 1140 µS/cm. The geothermal springs of Ca-HCO3 water type have an EC value of nearly 667 µS/cm and a temperature of nearly 26°C. The reservoir temperatures of the HGF geothermal system were calculated as 60–90°C and 108–160°C by silica and SO4-H2O oxygen isotope geothermometers, respectively. Stable isotope compositions (δ2H and δ18O) show that the geothermal well water is mixed with deeply circulated waters fed from higher elevations (∼ 830–1260 m), while the geothermal spring water is mixed with shallow cold water. The positive δ13C value (+3.01‰) indicates that the dissolved inorganic carbon (DIC) in the geothermal well water has no contribution from the atmospheric CO2 but originates in the metamorphic CO2 and marine limestones. However, the DIC in the geothermal springs is derived from C3 plants and silicate weathering. The values of 34SCDT show that the sulfate in the geothermal waters is due to the dissolution of sulfate minerals. The values of δ11B (-1.12 to +9.37 ‰) in the geothermal well and spring waters reflect both leaching of surrounding rocks and mantle-derived B. The reservoir rock may be Late Cretaceous-Permian limestones and Jurassic sandstones considering 87Sr/86Sr ratios (0.707108–0.707688) and δ7Li values (-7.44 to +6.18 ‰), whereas it might be Jurassic sandstones based on δ11B values. The strontium isotope composition of the geothermal spring water indicates the mixing of deep geothermal waters and cold groundwaters.



中文翻译:

土耳其哈夫扎(萨姆松)低焓地热系统中水的多同位素(O、H、C、S、Sr、B、Li)表征

在这项研究中,多同位素(O、H、C、S、Sr、B、Li)成分被用于进行地球化学表征,确定源岩和储集岩,并解释地热流体的水-岩相互作用机制。土耳其的低焓 Havza (Samsun) 地热田 (HGF)。Na-HCO 3水型地热水井口温度53℃,pH值接近7.7,EC值为1140 μS/cm。Ca-HCO 3水型地热泉的EC值接近667 µS/cm,温度接近26°C。HGF地热系统的储层温度分别通过二氧化硅和SO 4 -H 2 O氧同位素地温计计算为60-90°C和108-160°C 。稳定同位素组成(δ2 H 和 δ 18 O)表明地热井水与从较高海拔(~830-1260 m)供给的深循环水混合,而地热泉水与浅冷水混合。δ 13 C 正值(+3.01‰)表明地热井水中的溶解无机碳(DIC)没有来自大气CO 2 的贡献,而是来源于变质CO 2和海相石灰岩。然而,地热泉中的 DIC 来自 C3 植物和硅酸盐风化。34 S CDT值表明地热水中的硫酸盐是由于硫酸盐矿物的溶解。δ 11的值地热井和泉水中的 B (-1.12 to +9.37 ‰) 反映了围岩淋溶和幔源 B。考虑到87 Sr/ 86 Sr 比值 (0.707108) ,储层可能是晚白垩世-二叠纪灰岩和侏罗纪砂岩–0.707688) 和 δ 7 Li 值(-7.44 至 +6.18 ‰),而根据 δ 11 B 值可能是侏罗纪砂岩。地热泉水中的锶同位素组成表明深部地热水和冷地下水混合。

更新日期:2021-09-04
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