FlatChem ( IF 6.2 ) Pub Date : 2021-09-04 , DOI: 10.1016/j.flatc.2021.100280 Subramani Supriya 1 , Nikolas Antonatos 1 , Jan Luxa 1 , Rui Gusmão 1 , Zdeněk Sofer 1
Among 2D layered chalcogenides materials, platinum tellurides can form various stoichiometries with a layered structure that has attracted significant attention due to their yield of low overpotentials for hydrogen evolution reaction. In this work, layered Pt3Te4 and PtTe2 were synthesized and characterized, including their fundamental structural and electrochemical properties. We present a direct synthesis of Pt3Te4 and PtTe2 from the respective elements, resulting in a monoclinic and trigonal crystal structure, respectively. Their electrocatalytic properties were tested and compared with each other for the hydrogen evolution and oxygen reduction reactions, showing promising results for future catalytic applications.
中文翻译:
层状 Pt3Te4 和 PtTe2 用于电催化还原反应的比较
在二维层状硫属化物材料中,碲化铂可以形成各种化学计量的层状结构,由于其析氢反应的过电位较低,因此引起了广泛关注。在这项工作中,层状 Pt 3 Te 4和 PtTe 2被合成和表征,包括它们的基本结构和电化学特性。我们提出了 Pt 3 Te 4和 PtTe 2的直接合成从各自的元素,分别导致单斜和三方晶体结构。对它们的电催化性能进行了测试,并在析氢和氧还原反应方面进行了相互比较,显示了未来催化应用的有希望的结果。