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Decatungstate-Photocatalyzed Radical Addition of 9-Substituted Fluorenes to [60]Fullerene: A Mechanistic Approach
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-09-04 , DOI: 10.1002/ejoc.202100900 Michael Orfanopoulos 1 , Nikitas G. Malliaros 2
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-09-04 , DOI: 10.1002/ejoc.202100900 Michael Orfanopoulos 1 , Nikitas G. Malliaros 2
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A simple and efficient decatungstate catalyzed photochemical addition of 9-substituted fluorenyl radicals leads to the regioselective preparation of C60-fluorene dyads in good yields. The cleavage of the C−H or C−D bond in 9-position of fluorene is the rate-determining step of the reaction, as indicated by KIE measurements.
中文翻译：
9-取代芴与 [60] 富勒烯的脱钨酸光催化自由基加成：一种机械方法
9-取代芴基自由基的简单有效的十钨酸盐催化光化学加成导致C 60 -芴二元组的区域选择性制备，收率良好。如KIE 测量所示，芴的9-位 CH 或 CD键的断裂是反应的速率决定步骤。
更新日期：2021-09-13
中文翻译：
9-取代芴与 [60] 富勒烯的脱钨酸光催化自由基加成：一种机械方法
9-取代芴基自由基的简单有效的十钨酸盐催化光化学加成导致C 60 -芴二元组的区域选择性制备，收率良好。如KIE 测量所示，芴的9-位 CH 或 CD键的断裂是反应的速率决定步骤。
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