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N-Confused Pyritriphyrin: A New Class of Triphyrin and Its Calixphyrin Analogue
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-09-03 , DOI: 10.1002/ejoc.202100891
Mainak Das 1 , Deepak Singh 1 , Sangya Chitranshi 1 , M Murugavel 1 , Alagar Srinivasan 2
Affiliation  

The synthesized N-confused pyritriphyrin(3.3.1) begets a new class of triphyrin analogues. The reduction of N-confused triphyrin resulted in the formation of the respective calixphyrin analogue. The molecular structure of N-confused pyricalixphyrin is explicitly confirmed by single-crystal X-ray analyses and adopts partial ruffled conformation with exclusively amine pyrrole rings in the macrocyclic core.
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中文翻译:

N-Confused Pyritriphyrin:一类新的 Triphyrin 及其杯状卟啉类似物

合成的 N-confused pyritriphyrin(3.3.1) 产生了一类新的 triphyrin 类似物。N-混淆的三卟啉的减少导致相应杯状卟啉类似物的形成。N-confused pyricalixphyrin 的分子结构通过单晶 X 射线分析得到明确证实,并采用部分褶皱构象,大环核中仅含有胺吡咯环。
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更新日期:2021-10-01
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