N-Confused Pyritriphyrin: A New Class of Triphyrin and Its Calixphyrin Analogue,European Journal of Organic Chemistry

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N-Confused Pyritriphyrin: A New Class of Triphyrin and Its Calixphyrin Analogue
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-09-03 , DOI: 10.1002/ejoc.202100891
Mainak Das ₁ , Deepak Singh ₁ , Sangya Chitranshi ₁ , M Murugavel ₁ , Alagar Srinivasan ₂

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The synthesized N-confused pyritriphyrin(3.3.1) begets a new class of triphyrin analogues. The reduction of N-confused triphyrin resulted in the formation of the respective calixphyrin analogue. The molecular structure of N-confused pyricalixphyrin is explicitly confirmed by single-crystal X-ray analyses and adopts partial ruffled conformation with exclusively amine pyrrole rings in the macrocyclic core.

中文翻译：

N-Confused Pyritriphyrin：一类新的 Triphyrin 及其杯状卟啉类似物

合成的 N-confused pyritriphyrin(3.3.1) 产生了一类新的 triphyrin 类似物。N-混淆的三卟啉的减少导致相应杯状卟啉类似物的形成。N-confused pyricalixphyrin 的分子结构通过单晶 X 射线分析得到明确证实，并采用部分褶皱构象，大环核中仅含有胺吡咯环。

更新日期：2021-10-01

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