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Bidirectional Synthesis, Photophysical and Electrochemical Characterization of Polycyclic Quinones Using Benzocyclobutenes and Benzodicyclobutenes as Precursors
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-09-03 , DOI: 10.1002/ejoc.202100848
Amr M. Abdelmoniem 1 , Ismail A. Abdelhamid 1 , Holger Butenschön 2
Affiliation  

The synthesis of some new extended polycyclic quinones was achieved through a one-pot procedure comprising the cycloaddition of benzocyclobutene and benzodicyclobutene derivatives with benzoquinone or naphthoquinone. Notably, a highly symmetrical nonacene-hexaone could be prepared, albeit in low yields (5–7 %).
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中文翻译:

以苯并环丁烯和苯二环丁烯为前体的多环醌的双向合成、光物理和电化学表征

一些新的扩展多环醌的合成是通过一锅法合成的,包括苯并环丁烯和苯并二环丁烯衍生物与苯醌或萘醌的环加成。值得注意的是,可以制备高度对称的九苯-六酮,尽管产率较低(5-7%)。
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更新日期:2021-09-03
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