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Nucleophilic Phosphine Catalysis: The Untold Story
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-02 , DOI: 10.1002/ajoc.202100496 San Khong 1 , Telugu Venkatesh 1 , Ohyun Kwon 1
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-02 , DOI: 10.1002/ajoc.202100496 San Khong 1 , Telugu Venkatesh 1 , Ohyun Kwon 1
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To set the record straight: This Minireview provides insight into the early history of nucleophilic phosphine catalysis. The concepts of 1,4-addition of a tertiary phosphine to an α,β-enone and of equilibrium between the resulting phosphonium zwitterion and phosphonium ylide established a fundamental basis for the development of several classical transformations, including the Rauhut-Currier, Morita, McClure-Baizer-Anderson, and Oda reactions.
中文翻译：
亲核膦催化：不为人知的故事
为了澄清事实：这篇迷你评论深入了解了亲核膦催化的早期历史。叔膦与 α,β-烯酮 1,4-加成以及所得鏻两性离子和鏻叶立德之间平衡的概念为几种经典转化的发展奠定了基础，包括 Rauhut-Currier、Morita、麦克卢尔-贝泽-安德森和小田反应。
更新日期：2021-09-02
中文翻译：
亲核膦催化：不为人知的故事
为了澄清事实：这篇迷你评论深入了解了亲核膦催化的早期历史。叔膦与 α,β-烯酮 1,4-加成以及所得鏻两性离子和鏻叶立德之间平衡的概念为几种经典转化的发展奠定了基础，包括 Rauhut-Currier、Morita、麦克卢尔-贝泽-安德森和小田反应。
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