当前位置: X-MOL 学术J. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Correction to “NHC-Catalyzed Aza-Benzoin Condensation of N,N′-Dipyridin-2-yl Aminals with Aldehydes”
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2021-09-03 , DOI: 10.1021/acs.joc.1c02051
Justin S Lamb , Ryo Takashima , Yumiko Suzuki

The assignments of the signals located at 7.97 to 8.00 and 8.06 in CDCl3 were incorrect in Figure 2 on p 10228. They should be corrected as follows. Figure 2. Compound 2a in DMSO-d6 and CDCl3. Comparison of aminal 2a dissolved in DMSO-d6 (top) and CDCl3 (bottom) is shown. When aminal 2a is dissolved in DMSO-d6, the equilibrium is shifted heavily toward aminal 2a, allowing for the observation of aminal 2a. When aminal 2a is dissolved in CDCl3, the equilibrium is shifted heavily toward imine 2a′ and 2-aminopyridine, allowing for the clear observation of both imine 2a′ (blue triangles) and 2-aminopyridine (red circles). This article has not yet been cited by other publications. Figure 2. Compound 2a in DMSO-d6 and CDCl3. Comparison of aminal 2a dissolved in DMSO-d6 (top) and CDCl3 (bottom) is shown. When aminal 2a is dissolved in DMSO-d6, the equilibrium is shifted heavily toward aminal 2a, allowing for the observation of aminal 2a. When aminal 2a is dissolved in CDCl3, the equilibrium is shifted heavily toward imine 2a′ and 2-aminopyridine, allowing for the clear observation of both imine 2a′ (blue triangles) and 2-aminopyridine (red circles).

中文翻译:

对“NHC 催化的 N,N'-Dipyridin-2-yl Aminals 与醛的 Aza-Benzoin 缩合反应”的修正

在第 10228 页的图 2中,CDCl 3中位于 7.97 到 8.00 和 8.06 的信号的分配不正确。它们应按如下方式更正。图 2. DMSO- d 6和CDCl 3 中的化合物2a。显示了溶解在 DMSO- d 6(顶部)和 CDCl 3(底部)中的氨基2a 的比较。当 aminal 2a溶解在 DMSO- d 6 中时,平衡向 aminal 2a移动,允许观察 aminal 2a。当氨基2a溶解在 CDCl 3 中时,平衡向亚胺2a'和 2-氨基吡啶严重移动,从而可以清楚地观察亚胺2a'(蓝色三角形)和 2-氨基吡啶(红色圆圈)。这篇文章还没有被其他出版物引用。图 2. DMSO- d 6和CDCl 3 中的化合物2a。显示了溶解在 DMSO- d 6(顶部)和 CDCl 3(底部)中的氨基2a 的比较。当 aminal 2a溶解在 DMSO- d 6 中时,平衡向 aminal 2a移动,允许观察 aminal 2a. 当氨基2a溶解在 CDCl 3 中时,平衡向亚胺2a'和 2-氨基吡啶大幅移动,从而可以清楚地观察到亚胺2a'(蓝色三角形)和 2-氨基吡啶(红色圆圈)。
更新日期:2021-09-17
down
wechat
bug