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Recent progress in doping-induced structural and electronic modification in Cu–SnCo interconnected network enhanced efficient performance evidence for the hydrogen evolution reaction: current state and prospects
Journal of Porous Materials ( IF 2.5 ) Pub Date : 2021-05-04 , DOI: 10.1007/s10934-021-01084-2
Abdul Qayoom Mugheri , Muhammad Rafique Daudpoto , Arsalan Ahmed Mugheri , Dost Muhammad Kalhoro

A outperform and active non-noble electrocatalyst for hydrogen evolution reaction is hotspot in the current research activities for the hydrogen production with zero carbon dioxide emission. The requirement for stable and durable electrocatalysts for active HER is of exhibit high challenges for the present and future generations. Considering the role of single-component systems of Sn, Co, and Cu, for energy applications, here we present the ternary oxide system of these three elements with a ratio of copper nanoparticles. In a basic medium, the best 46% Cu-doped structure exhibited the highest response for hydrogen production by giving 10 mA/cm2 at 0.31 V. The Tafel slope of this composition (46% Cu) of material is the lowest ever reported for hydrogen production for Cu-doped electrocatalysts. The electrocatalysts exhibit excellent stability and high durability. Chronopotentiometry test was performed at 10 mA/cm2 & current density suffers no significant loss in the potential for 10 hours in basic media, respectively. The Cu–SnCo system is directly used nano electrocatalyst for efficient HER. The key element in the success of newly developed electrocatalyst is the greater amount of copper nanoparticles which has played dominant role in hydrogen gas production. To understand new fundamental questions related to electrocatalyst design to achieve very effective and for the stable nonprecious electrocatalysts for overall water splitting and to strengthen renewable energy reservoirs and to minimize the global warming effects. This nanocomposite catalyst is an alternative and promising material for other co-existing applications such as energy storage devices. The developed material can be applied in the other competing fields such as lithium ion batteries, solar cells, energy storage devices, and photochemical water splitting.



中文翻译:

Cu-SnCo互连网络中掺杂诱导结构和电子改性的最新进展增强了析氢反应的有效性能证据:现状和前景

用于析氢反应的性能优异且活性非贵重的电催化剂是当前二氧化碳零排放制氢研究活动的热点。活性 HER 对稳定耐用的电催化剂的需求对当代和后代都提出了很高的挑战。考虑到 Sn、Co 和 Cu 单组分系统在能源应用中的作用,我们在这里介绍了这三种元素的三元氧化物系统与铜纳米颗粒的比例。在基本介质中,最好的 46% Cu 掺杂结构通过提供 10 mA/cm 2表现出最高的产氢响应在 0.31 V 时。这种材料组成(46% 铜)的塔菲尔斜率是有史以来报道的铜掺杂电催化剂产氢的最低值。电催化剂表现出优异的稳定性和高耐久性。计时电位测试在 10 mA/cm 2 下进行电流密度分别在基本介质中 10 小时的电位没有显着损失。Cu-SnCo 系统直接用于高效 HER 的纳米电催化剂。新开发的电催化剂成功的关键因素是大量的铜纳米粒子,它在氢气生产中起主导作用。了解与电催化剂设计相关的新基本问题,以实现非常有效且稳定的非贵重电催化剂用于整体水分解并加强可再生能源库并最大限度地减少全球变暖效应。这种纳米复合催化剂是用于其他共存应用(如储能设备)的替代材料和有前途的材料。开发的材料可应用于其他竞争领域,如锂离子电池、

更新日期:2021-05-04
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